LearnViz Chemistry
Intermediate Topic 49 of 1102 Atomic Structure & Periodicity

Heisenberg Uncertainty Principle

It is impossible to determine simultaneously the exact position and momentum of a particle.

Practise Atomic Structure & Periodicity All Atomic Structure & Periodicity topics

In-depth explanation of Heisenberg Uncertainty Principle

The product of the uncertainties in position and momentum of a particle is at least h / 4 pi, so the more precisely one is known, the less precisely the other can be known. This limit is a fundamental property of nature and not a flaw in measuring instruments. A similar relation holds for energy and time. It means that electrons have no definite orbits, only probability distributions. The principle has direct consequences for the size and energy of atoms, because confining an electron to a small region raises its kinetic energy.

Going deeper: Heisenberg Uncertainty Principle

Key ideas: Position and momentum cannot both be known precisely: delta x x delta p is at least h / (4 pi), with h / 4 pi = 5.27 x 10^-35 J s. Solve for delta x = h / (4 pi m delta v). For an electron with delta v = 10^5 m per s, delta x is about 0.58 nm, bigger than an atom, so orbits are meaningless.

Common mistakes and connections: Students attribute it to measuring instruments disturbing the particle; it is a fundamental property of matter waves. It is negligible for large objects. It supports the idea of orbitals as probability regions and explains zero-point energy.

Visualization of Heisenberg Uncertainty Principle

A narrow position distribution means a broad spread in momentum: the more precisely an electron is located, the less precisely its momentum is known. The interactive lesson shows this as a live animation or chart.

Worked example and use case

Locating an electron to within 1.0 x 10^-11 m makes its speed uncertain by at least about 6 x 10^6 m/s.

Frequently asked questions about Heisenberg Uncertainty Principle

What is Heisenberg Uncertainty Principle?

It is impossible to determine simultaneously the exact position and momentum of a particle.

Is Heisenberg Uncertainty Principle a beginner, intermediate or advanced topic?

Heisenberg Uncertainty Principle is a intermediate topic in Atomic Structure & Periodicity. It builds on the vocabulary of beginner topics in this area.

What should I learn before Heisenberg Uncertainty Principle?

Study these earlier topics in Atomic Structure & Periodicity first: Bohr Energy Levels, Limitations of Bohr Model, de Broglie Hypothesis.

What comes after Heisenberg Uncertainty Principle?

The next topics in Atomic Structure & Periodicity are Wave Function and Schrodinger Equation.

Can I practise Heisenberg Uncertainty Principle with quizzes?

Yes. The interactive lesson includes a self-check question on Heisenberg Uncertainty Principle, and the Atomic Structure & Periodicity quiz draws on every topic in this area.

Where Heisenberg Uncertainty Principle fits in Atomic Structure & Periodicity

Heisenberg Uncertainty Principle is topic 49 of 115 in Atomic Structure & Periodicity.

Related topics

Browse all 115 topics in Atomic Structure & Periodicity