Combustion of Hydrocarbons
Hydrocarbons burn in oxygen to give carbon dioxide and water, releasing energy.
Hydrocarbons burn in oxygen to give carbon dioxide and water, releasing energy.
Combustion is the rapid reaction of a hydrocarbon with oxygen to release carbon dioxide, water and a large amount of energy. Complete combustion of an alkane follows the general equation CnH2n+2 plus (3n+1)/2 O2 giving n CO2 and (n+1) H2O. Insufficient oxygen produces incomplete combustion, which gives carbon monoxide and soot, a hazard that reduces the energy output. Alkanes with a higher proportion of hydrogen per carbon release more energy per gram, because each C-H bond formed contributes heat.
Key ideas: Complete combustion: CxHy plus (x plus y/4) O2 gives x CO2 plus y/2 H2O. Balance carbon first, then hydrogen, then oxygen. Heat of combustion per mole rises with carbon number: methane 890 kJ/mol, ethane 1560, propane 2220. Incomplete combustion gives CO or soot, and a yellow smoky flame for high carbon-to-hydrogen ratio (aromatics, alkynes).
Common mistakes and connections: Students forget that oxygen-limited combustion gives toxic carbon monoxide. Another error is balancing oxygen first and leaving fractional coefficients unresolved. Gas volume ratios follow Avogadro: 1 volume CH4 needs 2 volumes O2. Links to enthalpy of combustion, octane number and eudiometry problems.
Heat released per mole burned rises with carbon count as more C-H and C-C bonds become CO2 and H2O. The interactive lesson shows this as a live animation or chart.
Propane burns according to C3H8 plus 5 O2 giving 3 CO2 and 4 H2O.
Hydrocarbons burn in oxygen to give carbon dioxide and water, releasing energy.
Combustion of Hydrocarbons is a beginner topic in Organic Chemistry. It needs no earlier chemistry lessons and is a good starting point.
Study these earlier topics in Organic Chemistry first: Electrophiles and Nucleophiles, Reaction Types in Organic Chemistry, Free Radical Halogenation.
The next topics in Organic Chemistry are Cracking and Fractional Distillation of Crude Oil.
Yes. The interactive lesson includes a self-check question on Combustion of Hydrocarbons, and the Organic Chemistry quiz draws on every topic in this area.
Combustion of Hydrocarbons is topic 43 of 148 in Organic Chemistry.