Evaporation
Escape of higher-energy molecules from a liquid surface into the vapor phase.
Practise States of Matter & Solutions All States of Matter & Solutions topics
Escape of higher-energy molecules from a liquid surface into the vapor phase.
Practise States of Matter & Solutions All States of Matter & Solutions topics
Evaporation is the process by which molecules at the surface of a liquid gain enough energy to escape into the vapour phase. The fastest, most energetic molecules leave first, so the average kinetic energy and temperature of the remaining liquid fall, which makes evaporation a cooling process. The rate of evaporation increases with temperature, with a larger surface area, and with drier surrounding air. Unlike boiling, evaporation occurs only at the surface and at any temperature. It is the mechanism by which sweat cools the body.
Key ideas: Evaporation rate depends on temperature, surface area, humidity and airflow. It removes the latent heat of vaporization from the liquid, about 2260 J per gram for water, so sweating at 1 g per minute removes about 38 W. Evaporation proceeds until vapour pressure equals the equilibrium value in a closed container.
Common mistakes and connections: Students mistake evaporation for boiling; there are no bubbles and it occurs at any temperature. Another error is saying evaporation needs the liquid to reach its boiling point. In a closed container evaporation continues while condensation matches it, giving dynamic equilibrium. Links to vapour pressure, enthalpy of vaporization and cooling effects.
At the surface, the fastest molecules overcome attractions and escape; heating raises the fraction with enough energy so evaporation speeds up. The interactive lesson shows this as a live animation or chart.
A wet cloth dries faster in windy conditions because moving air carries water vapour away from its surface.
Escape of higher-energy molecules from a liquid surface into the vapor phase.
Evaporation is a beginner topic in States of Matter & Solutions. It needs no earlier chemistry lessons and is a good starting point.
Study these earlier topics in States of Matter & Solutions first: Liquefaction of Gases, Liquid State, Vapor Pressure.
The next topics in States of Matter & Solutions are Boiling Point and Normal Boiling Point.
Yes. The interactive lesson includes a self-check question on Evaporation, and the States of Matter & Solutions quiz draws on every topic in this area.
Evaporation is topic 36 of 109 in States of Matter & Solutions.